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Throw to Foot - Throw the hat to your foot as if it was a hatstand.
Hold the hat crown up above the shoulder with an inside grip.
Lift the leg and keep it straight, flexing the foot as much as you can. With a flick of the wrist throw the hat straight to the foot with a single spin.
This trick looks best if the throw is as straight as possible.
Foot to Head is a nice return trick from here.