A cigarette is tossed from behind the back and caught in the mouth. Then a kitchen match is lit and tossed behind the back and caught in the mouth to light the cigarette. Revival of Bobby May trick.
Peiro Brothers from Argentina, on the Ed Sullivan Show in 1965. The clip is from a 'tribute' clip show, which is why there's some superfluous narration at the beginning.
club stealing and runaround with hats and cigarette